hydrolytic$36471$ - traduzione in greco
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hydrolytic$36471$ - traduzione in greco

Dynamic kinetic resolution; Parallel kinetic resolution; Parallel Kinetic Resolution; Enzymatic resolution; Hydrolytic kinetic resolution
  • Bäckvall's ruthenium catalyst for racemization in chemoenzymatic dynamic kinetic resolution of secondary alcohols
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  • Fu's planar chiral DMAP (-)-catalyst for the kinetic resolution of secondary alcohols
  • Ruthenium catalyst used by Fu for racemization of secondary alcohols
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  • Fu's (-)-PPY* catalyst (left) and novel acylating agent (right)
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  • Hoveyda and Schrock's catalyst for ring closing metathesis kinetic resolution
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  • Jacobsen's (R,R) (salen)-Cr catalyst for kinetic resolution of terminal epoxides via azide formation
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  • Jacobsen's (R,R) (salen)-Cr catalyst for hydrolytic kinetic resolution of terminal epoxides
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  • Noyori's (R)-BINAP Ru catalyst for the hydrogenative kinetic resolution of allylic alcohols
  • Noyori's (S,S) catalyst for the transfer hydrogenation/kinetic resolution of secondary alcohols
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  • (S)-SYNPHOS
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  • Uemura and Hidai's catalyst for transfer hydrogenation/kinetic resolution of secondary alcohols

hydrolytic      
adj. υδρολυτικός

Definizione

hydrolyse
['h??dr?l??z]
(also hydrolyze)
¦ verb Chemistry break down (a compound) by chemical reaction with water.

Wikipedia

Kinetic resolution

In organic chemistry, kinetic resolution is a means of differentiating two enantiomers in a racemic mixture. In kinetic resolution, two enantiomers react with different reaction rates in a chemical reaction with a chiral catalyst or reagent, resulting in an enantioenriched sample of the less reactive enantiomer. As opposed to chiral resolution, kinetic resolution does not rely on different physical properties of diastereomeric products, but rather on the different chemical properties of the racemic starting materials. The enantiomeric excess (ee) of the unreacted starting material continually rises as more product is formed, reaching 100% just before full completion of the reaction. Kinetic resolution relies upon differences in reactivity between enantiomers or enantiomeric complexes.

Kinetic resolution can be used for the preparation of chiral molecules in organic synthesis. Kinetic resolution reactions utilizing purely synthetic reagents and catalysts are much less common than the use of enzymatic kinetic resolution in application towards organic synthesis, although a number of useful synthetic techniques have been developed in the past 30 years.